WebSep 2014 - Sep 20243 years 1 month. Göteborg, Sverige. The aim of this project was to provide a framework for studying the net power generation by a thermo-acoustic … WebIn organic chemistry, kinetic resolution is a means of differentiating two enantiomers in a racemic mixture.In kinetic resolution, two enantiomers react with different reaction rates in a chemical reaction with a chiral catalyst or reagent, resulting in an enantioenriched sample of the less reactive enantiomer. As opposed to chiral resolution, kinetic resolution …
Dynamic Kinetic Resolution via Asymmetric Conjugate …
WebJan 31, 2024 · Dynamic reductive kinetic resolution Ketoreductase Directed evolution Asymmetric synthesis Recent years have witnessed the growing applications of … WebJan 5, 2016 · Dynamic Reductive Kinetic Resolution of Benzyl Ketones using Alcohol Dehydrogenases and Anion Exchange Resins. Daniel Méndez-Sánchez, Daniel Méndez-Sánchez. Organic and Inorganic Chemistry Department, Biotechnology Institute of Asturias (IUBA), University of Oviedo, Avenida Julián Clavería s/n, 33006 Oviedo, Spain, Fax: … graines betterave rouge
Dynamic Reductive Kinetic Resolution of Benzyl Ketones using …
WebAug 19, 2024 · At last, although these enzymes provide excellent alternatives for the preparation of chiral sulfoxides, the natural defect of 50% maximum theoretical yield for kinetic resolution cannot be ignored. Developing dynamic reduction-oxidation enzymatic cascade reaction might be a solution to overcoming this drawback in the future. Author … WebAug 31, 2024 · The reactions described herein followed a biocatalytic dynamic kinetic reductive resolution (DKRR) pathway, which is reported for the first time with such … WebOct 11, 2024 · Here, we report a reductive enzymatic dynamic kinetic resolution for the preparation of (S)-2-phenylpropanol. The xylose reductase from Candida tenuis (CtXR, aldo–keto reductase superfamily) showed a basal activity with rac-2-phenylpropanal and moderate preference for the (S)-enantiomer. We investigated five enzyme variants with … graines de basilic thai